kram1032
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« Reply #1 on: April 05, 2014, 03:38:31 PM » |
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You have a bit of a wrong notion of Entropy there. - Most people have.
First of all, Entropy is a statistical effect. As such, systems of only few particles pretty much do not obey it. Thus, if the universe started "infinitely compressed", it would have been pretty much like a single particle and, as such, wouldn't really have been affected by entropy at all. Instead, it would have been subject to quantum fluctuations which, at the tiny scale everything once was, would have been incredibly high. These fluctuations likely are what started the expansion.
Second, take two cups of milk that have the same number of particles in them, the same volume, the same shape and stand in the same room with equal temperature everywhere. Those two cups of milk do not see any increase in entropy. The number of combination is equal in them. Now, if you cool one of them down, you constrain the movement of individual milk molecules. Eventually, it'll freeze, e.g. build solid crystals. These solid structures are very limited in the way they can move. They are lower entropy than the other glass of milk. There are only so many ways in which crystals can be formed. If you, instead, heat the milk up, it will eventually start to boil. This gas is a new state which adds possible configurations. Things suddenly can be more apart while, before, they had to be tightly packed together. In liquids, there are weak bonds between neighbouring molecules. They can easily be moved around but there is a small force preventing them to split up (surface tension) which reduces the possible configurations. In a gas, basically everything is possible, as long as the individual atoms are kept intact. In a plasma you go up a step. Here, electrons are no longer bound to atomic cores, so they move freely. There no longer are molecules. Way more ways in which electrons and atomic cores can be arranged are now available. And if you go even further, eventually even the cores break apart and you get a quark-gluon-plasma, where individual quarks are no longer bound to each other. Even more possible configurations now exist.
Entropy only has to increase for a whole system. Locally, it can decrease. - that happened in the frozen milk. To cool down something, you need to warm up something else. Air Conditioning works that way: It "pumps" heat out of one system, into another. That's why the stream of air that typically goes outside is actually rather hot. It increases the entropy in the world while cooling a room, reducing its entropy.
The often-mentioned analogy of sheep initially starting in a corner of a field and then spreading out is a bit flawed.
This would only be correct, if the sheep first are fenced off to only have a tiny space. They can't move around easily, they need to squeeze past each other. Then, if the fence is removed, they can spread over a far wider area, they stand in more different configurations.
If, instead, you never have a fence, and the sheep happen to stand close to each other, that's just one of the possible configurations.
Decreasing Volume, increasing particle count or decreasing average particle speed all reduce entropy. (More, slower sheep in a smaller volume can't find as many possible ways to stand) The opposite things increase entropy.
Changing none of those variables keeps entropy on the same level. The glass of milk doesn't suddenly have an increase in entropy while it sits in that room at equilibrium.
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